Organic chemistry poon brown 6th edition pdf download

Organic chemistry poon brown 6th edition pdf download

organic chemistry poon brown 6th edition pdf download

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Century egg

A Chinese egg product made by preserving eggs in a mixture of clay, ash, salt, quicklime, and rice hulls
A century egg sliced open
Alternative namespreserved egg, hundred-year egg, thousand-year egg, thousand-year-old egg, millennium egg, black egg, blacking egg, skin egg
Place of originChina
Main ingredientsEgg preserved in clay, ash, salt, quicklime, and rice hulls
Variationsduck, chicken or quail eggs

Century eggs (Chinese: 皮蛋; pinyin: pídàn; Jyutping: pei4 daan2), also known as preserved eggs, hundred-year eggs, thousand-year eggs, thousand-year-old eggs, millennium eggs, skin eggs, or black eggs, are a Chinese preserved egg product made by processing duck, chicken or quail eggs in a mixture of clay, ash, salt, quicklime, and rice hulls for several weeks to several months, depending on the method of processing.[1]

Through the process, the yolk becomes a dark green to grey color, with a creamy consistency and strong flavor due to the hydrogen sulfide and ammonia present, while the white becomes a dark brown, translucent jelly with a salty flavor. The transforming agent in the century egg is an alkalinesalt, which gradually raises the pH of the egg to around 9–12, during the curing process.[2] This chemical process breaks down some of the complex, flavorless proteins and fats, which produces a variety of smaller flavorful compounds.

Some eggs have patterns near the surface of the egg white which are likened to pine branches. These patterned eggs are regarded as having better quality than the normal century eggs and are called Songhua egg, also known as pine flower egg, pine-patterned eggs(Chinese: 松花蛋). In , 3 million ton of Songhua eggs were consumed in China.[3]

History[edit]

The method for creating century eggs likely came about through the need to preserve eggs in times of plenty by coating them in alkaline clay, which is similar to methods of egg preservation in some Western cultures.[4] The clay hardens around the egg and results in the curing and creation of century eggs instead of spoiled eggs.

The century egg has at least four centuries of history behind its production. Its discovery, though not verifiable, was said to have occurred around years ago in Hunan during the Ming Dynasty, when a homeowner discovered duck eggs in a shallow pool of slaked lime that was used for mortar during construction of his home two months before. Upon tasting the eggs, he set out to produce more&#;– this time with the addition of salt to improve their flavor&#;– resulting in the present recipe of the century egg.[5] An alternate story involves a young duck farmer by the name of Shuige (水哥, lit. water-brother), also from Hunan, leaving duck eggs in the garden of a woman by the name of Songmei (松妹, lit. pine-sister) as a courting gesture. The eggs were not discovered until the woman cleaned out the ash pit half a month later where they had turned into century eggs. In her honour, the farmer named the transformed eggs with their delicate crystalline patterns on their surfaces "pine-patterned eggs".[6]

Methods[edit]

Traditional[edit]

The traditional method for producing century eggs developed through improvement of the aforementioned primitive process. Instead of using just clay, a mixture of wood ash, calcium oxide, and salt is included in the plastering mixture, thereby increasing its pH and sodium content. The addition of calcium oxide and wood ash to the mixture lowers the risk of spoilage and also increases the speed of the process. A recipe for creating century eggs starts with the infusion of &#;kg (3&#;lb) of tea in boiling water. To the tea, &#;kg (3&#;lb) of calcium oxide (&#;kg or 7&#;lb, if done in winter), &#;kg (9&#;lb) of sea salt, and &#;kg (7&#;lb) of ash from burned oak is mixed into a smooth paste. Each egg is individually covered by hand, with gloves worn to protect the skin from chemical burns. It is then rolled in a mass of rice chaff, to keep the eggs from adhering to one another, before the eggs are placed in cloth-covered jars or tightly woven baskets. The mud slowly dries and hardens into a crust over several months. The eggs are then ready for consumption.[7]

Modern[edit]

Even though the traditional method is still widely practiced, modern understanding of the chemistry behind the formation of century eggs has led to many simplifications in the recipe. Today, soaking raw eggs in a solution of table salt, calcium hydroxide and sodium carbonate for 10 days, followed by several weeks of aging while wrapped in plastic, is said to achieve the same effect as the traditional method. This is because the chemical reaction needed to produce century eggs is accomplished by introducing hydroxide and sodiumions into the egg, regardless of the method used.

The extremely toxic compound lead(II) oxide speeds up the reactions which create century eggs, leading to its use by some unscrupulous producers,[4] whereas zinc oxide is now the recommended alternative.[8] Although zinc is essential for life, excessive zinc consumption can lead to copper deficiency, and the finished product should have its zinc level assessed for safety.

Uses[edit]

Century eggs can be eaten without further preparation other than peeling and rinsing them&#;– on their own, or as a side dish. As an hors d'œuvre, the Cantonese wrap chunks of this egg with slices of pickled ginger root (sometimes sold on a stick as street food). A Shanghainese recipe mixes chopped century eggs with chilled tofu. In Taiwan, it is popular to eat sliced century eggs placed on top of cold tofu with katsuobushi, soy sauce, and sesame oil, in a style similar to Japanesehiyayakko. A variation of this recipe common in northern China is to slice century eggs over chilled silken (soft) tofu, adding liberal quantities of shredded young ginger and chopped spring onions as a topping, and then drizzling light soy sauce and sesame oil over the dish, to taste. They are also used in a dish called old-and-fresh eggs, where chopped century eggs are combined with (or used to top) an omelette made with fresh eggs.[9] The century eggs may also be cut into chunks and stir fried with vegetables, which is most commonly found in Taiwanese cuisine.

Some Chinese households cut them up into small chunks and cook them with rice porridge to create "century egg and lean pork congee" (Chinese: 皮蛋瘦肉粥; pinyin: pídàn shòuròu zhōu). This is sometimes served in dim sum restaurants. Rice congee, lean pork, and century egg are the main ingredients. Peeled century eggs are cut into quarters or eighths and simmered with the seasoned marinated lean slivers of pork until both ingredients are cooked into the rice congee. Fried dough sticks known as youtiao are commonly eaten with century egg congee. Another common variation of this dish is the addition of salted duck eggs into the congee mixture.

At special events like wedding banquets or birthday parties, a first course platter of sliced barbecued pork, pickledbaby leeks, sliced abalone, pickledjuliennedcarrots, pickledjulienneddaikon radish, seasoned julienned jellyfish, sliced pork, head cheese and the quartered century eggs is served. This is called a lahng-poon in Cantonese, which simply means "cold dish".

Misconception and etymology[edit]

Century eggs are sometimes avoided due to the belief that they are prepared by soaking eggs in horseurine, but there is no good evidence to support this, and furthermore urine is generally not alkaline.[10] In Thai and Lao, the common word for century egg translates to "horse urine egg", due to the distinctive urine-like odor of the food:

It's also possible that century eggs are being confused for virgin boy eggs, which actually are prepared in urine (though not horse urine).

Safety[edit]

Heavy metals have been used to speed up the process to turn more profit for less time and artificially increase the quality of the preserved egg. It was an unscrupulous practice in some small factories but it became rampant in China and forced many honest manufacturers to label their boxes "Lead Free" after the scandal went mainstream in Thirty factories in Nanchang county were found to be using industrial quality copper sulphate which was contaminated with arsenic, lead, cadmium, and other heavy metals and toxic chemicals to make eggs more translucent, lessen odor, provide smoother texture and encourage faster curing.[11][12] The Chinese government has over the years been trying to regulate food additives and license law abiding establishments to combat the food safety incidents in China posed by bad manufacturing practice.

Gallery[edit]

  • Century egg coated in a caustic mixture of mud and rice husk

  • Century egg showing snow-flake/pine-branch (松花, sōnghuā) patterns. These patterns are dendrites of various salts.

  • Arranged century egg on a plate

  • Century eggs for sale in Hong Kong

  • Pink century eggs in Laos

See also[edit]

References[edit]

Citations[edit]

  1. ^Moskvitch, Katia (29 March ). "Black eggs and ripe guava lead Taiwan's tech revolution". BBC News. Retrieved 29 March
  2. ^McGee, Harold (). On Food and Cooking: The Science and Lore of the Kitchen. Scribner. p.&#; ISBN&#;.
  3. ^[1], "一种松花皮蛋抗菌增香保鲜料及松花皮蛋的制作方法", issued &#;
  4. ^ abHou, Xiangchuan (). "Hunger and technology: Egg preservation in China". Food and Nutrition Bulletin. The United Nations University Press. 3 (2): 1–4. doi/ ISBN&#;.
  5. ^益阳市政府网 (). "益阳名优特产:松花皮蛋".[dead link]
  6. ^Zee, A. (). Swallowing Clouds. Touchstone. pp.&#;– ISBN&#;.
  7. ^"变蛋 Bian Dan "Transformation Eggs"". Purple Cloud. Retrieved
  8. ^Chen, JrWei; Su, HouPin (). "A new process for preparing spots-free pidan". Journal of the Chinese Society of Animal Science. 33 (1): 79–
  9. ^Billy. "Three Emperor Egg". www.cronistalascolonias.com.ar Archived from the original on Retrieved
  10. ^Helmenstine, Anne Marie. "Are Century Eggs Soaked in Horse Urine?" www.cronistalascolonias.com.ar. Thursday 16 October Retrieved on 20 October
  11. ^Li Jing (16 June ). "Preserved egg companies shut in toxic chemical scandal". South China Morning Post. Retrieved 17 November
  12. ^Nuwer, Rachel (18 June ). "Unless You Like Toxic Chemicals, Skip This Chinese Delicacy". Smithsonian Magazine. Retrieved 17 November

Sources[edit]

External links[edit]

Источник: www.cronistalascolonias.com.ar

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